Química sostenible

Proyecto 1: “Química sostenible: Catalizadores moleculares y supramoleculares altamente selectivos, estables y energéticamente eficientes en reacciones químicas”
Investigador principal: Avelino Corma
Equipo investigador: Vicente Fornés Seguí y a Germán I. Sastre Navarro

    Lista de publicaciones:

  • T. Blasco, A. Corma

    “Study of the Beckmann rearrangement of acetophenone oxime over porous solids by means of solid state NMR spectroscopy.”

    PCCP (2008) En prensa

  • B. Harzubaru, A. Corma, F. Rey, J.L. Jorda, D. Anaias, L. D. Carlos, J. Rocha

    “A miniaturized linear Ph sensor based on highly photoluminescent sefl-assembled europium (III) metal-organic framework

    Angew. Chem. Int. Ed. 48(35) 6476-9 (2009)

  • F. Gao, P. Botella, A. Corma, J. Blesa, L. Dong

    “Monodispersed mesoporous silica nanoparticles with very large pores for enhanced adsorption and release DNA.”

    J. Phys. Chem. (2009) Vol. 113 (6),1796-1804.

  • F. Gao, P. Botella, A. Corma, J. Blesa, L. Dong

    “Monodispersed mesoporous silica nanoparticles with very large pores for enhanced adsorption and release DNA.”

    J. Phys. Chem. (2009) Vol. 113 (6),1796-1804.

  • A. Corma, M. Boronat, F. Illas

    “Active Sites for H2 dissociation in Au/TiO2 and the role of the support”

    J. Phys. Chem. (2009) Vol. 24,282-292.

  • A. Corma, A. Leyva

    “Isolable gold (I) complexes having one low-coordinating ligand as catalysts for the selective hydration of substituted alkynes at room temperature without acidic promoters.”

    J. Organic Chemistry (2009. Vol. 74(5), 2067-2074.

  • P.Krawiec, E. Kockrick, L. Borchardt, D. Geiger, A. Corma, S. Kaskel

    “Ordered Mesoporous Carbide Derived Carbons: Novel Materials for Catalysis and Adsorption.”

    J. of Physical Chemistry (2009). Vol. 113 (18), 7755-7761.

  • M. Boronat, P. Concepción, A. Corma, M. T. Navarro, M. Renz, S.Valencia

    “Reactivity in the Confined Spaces of Zeolites: The interplay between spectroscopy and theory to develop Structure-Activity Relationships for Catalysis.”

    Physical Chemistry Chemical Physics (2009). Vol.11(16), 2876-2884.

  • A. Corma, F. Llopis, C. Martinez, G. Sastre, S. Valencia

    “The benefit of multipore zeolites: catalytic behaviour of zeolites with intersecting channels of different sizes for alkylation reactions”

    J. Catal. 268(1), 9-17 (2009)

  • M. J. Climent, A. Corma, S. Iborra, L. Santos

    “Multisite solid catalyst for cascade reactions: the direct synthesis of benzodiazepines from nitro compounds”

    Chem. Eurp. J, 15(35), 8834-41 (2009)

  • L. Santos, P. Serna, A. Corma

    “Chemoselective synthesis of substituted imines, secondary amines, and beta-amino carbonyl compounds from nitroaromatics through cascade reactions on gold catalyst”

    Chem. Eur. J. 15(33), 8196-203 (2009)

  • P. Serna, P. Concepcion, A. Corma

    “Design of highly active and chemoselective bimetallic gold-platinum hydrogenation catalysts through kinetic and isotopic Studies”

    Journal of Catalysis. 265(1), 19-25 (2009)

  • O. Casanova, S. Iborra, A. Corma

    “Biomass into chemicals: One pot-base free oxidative esterification of 5-hydroxymethyl-2-furfural into 2,5-dimethylfuroate with gold on nanoparticulated ceria”

    Journal of Catalysis. 265(1), 109-116 (2009)

  • M. Climent, A. Corma, Sara Iborra

    “Mono- and Multisite Solid Catalysts in Cascade Reactions for Chemical Process Intensification”

    ChemSusChem. 2(6), 500-506 (2009)

  • A. Corma, M. Diaz-Cabanas, J. Jorda, F. Rey, K. Boulahya, J. Gonzalez-Calbet

    “High-Resolution Transmission Electron Microscopy (HRTEM) and X-ray Diffraction (XRD) Study of the Intergrowth in Zeolites ITQ-13/ITQ-34”

    Journal of Physical Chemistry C. 113(21), 9305-9308 (2009)

  • A. Corma, M. Navarro, F. Rey, V. Ruiz, M. Sabater

    “Direct Synthesis of a Photoactive Inorganic-Organic Mesostructured Hybrid Material and its Application as a Photocatalyst”

    ChemPhysChem. 10(7), 1084-1089 (2009)

  • C. Aprile, A. Corma, M. Domine, H. Garcia, C. Mitchell

    “A cascade aerobic epoxidation of alkenes over Au/CeO2 and Ti-mesoporous material by “in situ” formed peroxides”

    Journal of Catalysis. 264(1), 44-53 (2009)

  • J. Sun, C, Bonneau, A. Cantin, A. Corma, M. Diaz-Cabanas, M. Moliner, D. Zhang, M. Li, X. Zou

    “The ITQ-37 mesoporous chiral zeolite”

    Nature (London, United Kingdom). 458(7242), 1154-1157 (2009)

  • A. Corma, I. Dominguez, A. Domenech, V. Fornes, C. Gomez-Garcia, T. Rodenas, M. Sabater

    “Enantioselective epoxidation of olefins with molecular oxyden catalyzed by gold(III): A dual pathway for oxygen transfer”

    Journal of Catalysis. 265(2), 238-244 (2009)

  • A. Corma, F. Llabres I Zamena, C. Prestipino, M. Renz, S. Valencia

    “Water Resistant, Catalytically Active Nb and Ta Isolated Lewis Acid Sites, Homogeneously Distributed by Direct Synthesis in a Beta Zeolite”

    Journal of Physical Chemistry C. 113(26), 11306-11315 (2009)

  • A. Leyva, X. Zhang, A. Corma

    “Chemoselective hydroboration of alkynes vs. alkenes over gold catalysts”

    Chem. Commun. 33, 4947- 9 (2009)

  • A. Corma, M. Diaz-Cabanas, J. Jorda, F. Rey, K. Boulahya, J. Gonzalez-Calbet

    “High-Resolution Transmission Electron Microscopy (HRTEM) and X-ray Diffraction (XRD) Study of the Intergrowth in Zeolites ITQ-13/ITQ-34”

    Journal of Physical Chemistry C. 113(21), 9305-9308 (2009)

  • A. Leyva, A. Corma

    “Reusable Gold(I) Catalysts with Unique Regioselectivity for Intermolecular Hydroamination of Alkynes”

    Advanced Synthesis & Catalysis 351(17), 2876 (2009)

  • J. Jiang, J. Yu, A. Corma

    “Extralarge Pore zeolites Bridging the Gap Between Micro and mesoporous Structures”

    Angew. Chem. Int. Ed. (2009).

  • P. Serna, M. Lopez-Haro, J. Calvino, A. Corma

    “Selective hydrogenation of nitrocyclohexane to cyclohexanone oxime with H2 on decorated Pt nanoparticles”

    Journal of Catalysis. 263(2), 328-334 (2009)

  • A.Corma, T. Rodenas, M. J. Sabater

    “A Bifunctional Pd/MgO Solid Catalyst for the One-Pot Selective N-Monoalkylation of Amines with Alcohols”

    Chem. A. Eur. J. 16(1), 254-260 (2010)

  • R. Simancas, D. Dari, N. Velamazan, M.T. Navarro, A. Cantin, J.L. Jorda, G. Sastre, A. Corma, F. Rey

    “Modular Organic Structure-Directing Agents for the Synthesis of Zeolites “

    SCIENCE, 330(6008), 1219-1222 (2010)

  • O. de La Torre, M. Renz, A. Corma

    “Biomass to chemicals: Rearrangement of β-pinene epoxide into myrtanal with well-defined single-site substituted molecular sieves as reusable solid Lewis-acid catalysts”

    Appl. Catal., A. General 380(1-2), 165-171 (2010)

  • I.Luz, F. X. Llabres I Xamena, A. Corma

    “Bridging homogeneous and heterogeneous catalysis with MOFs: “Click” reactions with Cu-MOF catalysts“

    J. Catal. 276(1), 134-140 (2010)

  • O.Casanova, S. Iborra, A. Corma

    “Chemicals from biomass: Etherification of 5-hydroxymethyl-2-furfural (HMF) into 5,5′(oxy-bis(methylene))bis-2-furfural (OBMF) with solid catalysts “

    J. Catal. 275(2), 236-242 (2010)

  • A. Corma, M. Iglesias, F. X. Llabres I Xamena, F. Sanchez

    “Cu and Au Metal-Organic Frameworks Bridge the Gap between Homogeneous and Heterogeneous Catalysts for Alkene Cyclopropanation Reactions”

    Chem. A Eur. J. 16(32), 9789-9795 (2010)

  • J. Jiang, J. Yu, A. Corma

    “Extra-large-pore zeolite: bridging the gap between micro and mesoporous structure”

    Angew. Chem. Int. Ed. 49(18), 3120-45 (2010)

  • T. Blasco, A. Corma, S. Iborra, I. Lezcano-Gonzalez, R. Monton

    “In situ multinuclear solid-state NMR spectroscopy study of Beckmann rearrangement of cyclododecanone oxime in ionic liquids: The nature of catalytic sites”

    J. Catal. 275(1), 78-83 (2010)

  • S. Maheshwari, C. Martinez, M.T. Portilla, F.J. Llopis, A. Corma, M. Tsapatsis

    “Influence of layer structure preservation on the catalytic properties of the pillared zeolite MCM-36”

    J. Catal. 272(2), 298-308 (2010)

  • J.R. Cabrero-Antonino, A. Leyva-Perez, A. Corma

    “Iron-Catalysed Regio- and Stereoselective Head-to-Tail Dimerisation of Styrenes”

    Adv. Synth. Catal. 352(10), 1571-1576, (2010)

  • V. R. Ruiz, A. Corma, M. J. Sabater

    “New route for the synthesis of benzimidazoles by a one-pot multistep process with mono and bifunctional solid catalysts”

    Tetrahedron 66(3), 730-735 (2010)

  • N. Villandier, A. Corma

    “One pot catalytic conversion of cellulose into biodegradable surfactants”

    Chem. Commun. 46(24), 4408-4410 (2010)

  • G. Sastre, A. Corma

    “Predicting Structural Feasibility of Silica and Germania Zeolites”

    J. Phys. Chem. C 114(3), 1667-1673 (2010)

  • A.Corma, V.R. Ruiz, A. Leyva-Perez, M.J. Sabater

    “Regio- and Stereoselective Intermolecular Hydroalkoxylation of Alkynes Catalysed by Cationic Gold(I) Complexes”

    Adv. Synth. Catal. 352(10), 1701-1710 (2010)

  • J. Jiang, J.L. Jorda, M.J. Diaz-Cabanas, J. Yu, A. Corma

    “The synthesis of an extra-large-pore zeolite with double three-ring building units and a low framework density”

    Angew. Chem. Int. Ed. 49(29), 4986-8 (2010)

  • A. Roldán, M, Boronat, A. Corma, F. Illas

    “Theoretical Confirmation of the Enhanced Facility to Increase Oxygen Vacancy Concentration in TiO2 by Iron Doping”

    J. Phys. Chem. C 114(14), 6511-6517 (2010)

  • C. Veziri, M. Palomino, G. Karanikolos, A. Corma, N. Kanellopoulos, M. Tsapatsis

    “Toward Submicrometer c-Oriented Nanoporous Films with Unidimensional Pore

    Network: AFI Film Morphology Control by Precursor Mixture Manipulation”

    Chem. Mater. 22(4), 1492-1502, (2010)

  • M.T. Portilla, F.J. Llopis, C. Martinez, S. Valencia, A. Corma

    “Structure-reactivity relationship for aromatics transalkylation and isomerization process with TNU-9, MCM-22 and ZSM-5 zeolites, and their industrial implications “

    Appl. Catal. A: General 393(1-2), 257-268 (2011)

  • P. Botella, A. Corma, R.H. Carr, C.J. Mitchell

    “Towards an industrial synthesis of diaminodiphenylmethane (DADPM) using novel delaminated materials: A breakthrough step in the production of isocyanates for polyurethanes “

    Appl. Catal. A. General 398(1-2), 143-149 (2011)

  • A. Primo, P. Concepción, A. Corma

    “Synergy between the metal nanoparticles and the support for the hydrogenation of functionalized carboxylic acids to diols on Ru/TiO2 “

    Chem. Commun. 47(12), 3613-3615, (2011)

  • M. Moliner, J. González, M.T. Portilla, T. Willhammar, F. Rey, F.J. Llopis, X. Zou, A. Corma

    “A New Aluminosilicate Molecular Sieve with a System of Pores between Those of ZSM-5 and Beta Zeolite “

    J. Am. Chem. Soc. 133(24), 9497-9505 (2011)

  • M. Boronat, A. Corma, F. Illas, J. Radilla, T. Rodenas, M.J. Sabater

    “Mechanism of selective alcohol oxidation to aldehydes on gold catalysts: Influence of surface roughness on reactivity “

    J. Catal. 278(1), 50-58 (2011)

  • L. Alves, B. Ballesteros, M. Boronat, J.R. Cabrero-Antonino, P. Concepcion, A. Corma, M.A. Correa-Duarte, E. Mendoza

    “Synthesis and Stabilization of Subnanometric Gold Oxide Nanoparticles on Multiwalled Carbon Nanotubes and Their Catalytic Activity “

    J. Am. Chem. Soc. 133(26), 10251-10261 (2011)

  • A. Corma, T. Rodenas, M.J. Sabater

    “Monoalkylations with alcohols by a cascade reaction on bifunctional solid catalysts: Reaction kinetics and mechanism “

    J. Catal. 279(2), 319-327 (2011)

  • A. Primo, A. Corma, H. Garcia

    “Titania supported gold nanoparticles as photocatalyst “

    Phys. Chem. Chem. Phys. 13(3), 886-910 (2011)

  • A. Corma, M. Boronat, M. Climent, S. Iborra, R. Monto, M.J. Sabater.

    “A recyclable bifunctional acid–base organocatalyst with ionic liquid character. The role of site separation and spatial configuration on different condensation reactions”

    Phys. Chem. Chem. Phys., 2011, 13, 17255–17261

  • J. Jiang, J.L. Jorda, J. Yu, L.A. Baumes, E. Mugnaioli, M.J. Diaz-Cabanas, U. Kolb, A. Corma

    “Synthesis and Structure Determination of the Hierarchical Meso-Microporous Zeolite ITQ-43 “

    SCIENCE, 333(6046), 1131-1134 (2011)

  • A.Grirrane, H. Garcia, A.Corma, E.Alvarez

    “Intermolecular [2 + 2] cycloaddition of alkene catalyzed by Au(I) complexes. What are the catalytic sites involved?

    ACS Catal.1 (12), 1647-1653 (2011)

  • A. Corma, T. Rodenas, M.J.Sabater

    “Aerobic oxidation of thiols to disulfides by heterogeneous gold catalysts”

    Chem. Sci. 3(2), 398-404 (2012)

  • F.G. Cirujano, F. X. Llabres I Xamena, A. Corma

    “MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst “

    Dalton Trans. 41(14), 4249-4254, (2012)

  • I. Luz, F.X. Llabres I Xamena, A. Corma

    “Bridging homogeneous and heterogeneous catalysis with MOFs: Cu-MOFs as solid catalysts for three-component coupling and cyclization reactions for the synthesis of propargylamines, indoles and imidazopyridines”

    J. Catal, 285(1), 285-291 (2012)

  • M.J. Climent, A. Corma, J.C. Hernández, A.B. Hungría, S. Iborra, S. Martínez-Silvestre

    “Biomass into chemicals: One-pot two- and three-step synthesis of quinoxalines from biomass-derived glycols and 1,2-dinitrobenzene derivatives using supported gold nanoparticles as catalysts”

    J. Catal. 292 (2012) 118–129

  • A. Pulido, P. Concepcion, M. Boronat, A.Corma

    “Aerobic epoxidation of propene over silver (1 1 1) and (1 0 0) facet catalysts ”

    J. Catal. 292, 138-147. (2012)

  • T. Willhammar, J. Sun, W. Wan, P. Oleynikov, D. Zhang, X. Zou, M. Moliner, J. Gonzalez, C. Martinez, F. Rey

    “Structure and catalytic properties of the most complex intergrown zeolite ITQ-39 determined by electron crystallography “

    Nature Chem. 4(3), 188-194, (2012)

  • A. Cabrero-Antonino, A.Leyva-Perez Antonio, A. Corma

    “Regioselective Hydration of Alkynes by Iron(III) Lewis/Bronsted Catalysis ”

    Chemistry (Weinheim an der Bergstrasse, Germany) (2012)

  • F. Llabres I Xamena, F. Cirujano, A. Corma

    “An unexpected bifunctional acid base catalysis in IRMOF-3 for Knoevenagel condensation reactions”

    Microporous Mesoporous Mater. 157, 112-117, (2012)

  • S. Laursen, D. Combita, A.B. Hungria, M. Boronat, A. Corma

    “First-principles design of highly active and selective catalysts for phosgene-free synthesis of aromatic polyurethanes”

    Angew. Chem. Inter. Ed. 124, 1-5, (2012)